Hi Steven,
As your going to mould a helmet, you do not want make the mould out of one layer of silicone, you want to build the mould up in stages.
First, ensure you cover the lid with some form of release agent, as your lid is plastic, a PVA Release Agent should be fine.
Take a small quantity of silicon with no thickener, and stipple it over the helmet ensuring you use the brush to push the silicone into all of the details area's. Take your time.
Once that starts to dry you can then apply a second coat, with some thickener added, then a 3rd thicker coat. You mould needs it to be between half and 1" thick. You can make your silicone batches in small quantities, if you work with someone they can whip up another batch of silicone quickly if you run out.
I am assuming your going to back the mould with Fibreglass, if so, once your silicone is dry, add a layer of resin then lay your fibreglass. Making sure you stipple each layer and then roll with a stippled roller if you have one. Put 3 to 4 layers of fibreglass and let it all cure, leave it overnight and your mould should be ready to cast from.
Just take your time, have a look at some of these YT vids and they will help you.
http://www.youtube.com/user/brickinthey ... w=0&page=1Best of Luck
Loz